Binary non-additive hard sphere mixtures: fluid demixing, asymptotic decay of correlations and free fluid interfaces
نویسندگان
چکیده
منابع مشابه
Elusiveness of fluid-fluid demixing in additive hard-core mixtures.
The conjecture that when an additive hard-core mixture phase separates when one of the phases is spatially ordered, well supported by considerable evidence, is in contradiction with some simulations of a binary mixture of hard cubes on cubic lattices. By extending Rosenfeld's fundamental measure theory to lattice models we show that the phase behavior of this mixture is far more complex than si...
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Using Monte Carlo simulation, we study the influence of geometric confinement on demixing for a series of symmetric non-additive hard spheres mixtures confined in slit pores. We consider both a wide range of positive non-additivities and a series of pore widths, ranging from the pure two dimensional limit to a large pore width where results are close to the bulk three dimensional case. Critical...
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ژورنال
عنوان ژورنال: Journal of Physics: Condensed Matter
سال: 2010
ISSN: 0953-8984,1361-648X
DOI: 10.1088/0953-8984/22/32/325108